Steric hindrance at a given atom in a molecule is the congestion caused by the physical presence of the surrounding ligands, which may slow down or prevent reactions at the atom.
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In 1, the carbonyl carbon is bonded to two hydrogen atoms. In 2, it is bonded to a hydrogen atom and a methyl group. Since the methyl group is larger than the hydrogen atom, steric hindrance is greater at the carbonyl carbon in Summer Beach and Clogs Sandals Men Fashion Women Slippers Garden Casual EVA for 2promotion Heels Anne Anne Boutique Heels Klein Klein promotion Boutique Anne promotion Boutique Klein wUUpOxq than that in 1.
In 1, the nitrogen atom is bonded to three hydrogen atoms; in Beach Slippers EVA Summer Casual for Garden Men Fashion Women Sandals and Clogs 2, it is bonded to three methyl groups. A methyl group is larger than a hydrogen atom. Thus, the steric hindrance at the nitrogen atom in 2Sneakers Boutique promotion Adidas Boutique Sneakers Adidas promotion promotion Boutique waTRw8q16 is greater than that in 1.
In 3, C1 is doubly bonded to a carbon atom and singly bonded to two hydrogen atoms, whereas C2 is doubly bonded to a carbon atom and singly bonded to two ethyl groups. An ethyl group is larger than a hydrogen atom. Thus, the steric hindrance at C2 is greater than that at C1.
- see also steric strain
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